EXPERIMENT 51 · PHYSICS LABORATORY
The Potentiometer: Accurate Measurement and Comparison of Electromotive Forces
To calibrate a slide-wire potentiometer using a Weston standard cell, determine the uniform potential gradient along the slide wire, compare the electromotive forces of dry and primary cells at null balance without drawing current, and verify that cell EMF is strictly proportional to balancing length. Explore a virtual apparatus, collect readings and analyse a graph.
FOLLOW THE METHOD
A reason behind every step.
To calibrate a slide-wire potentiometer using a Weston standard cell, determine the uniform potential gradient along the slide wire, compare the electromotive forces of dry and primary cells at null balance without drawing current, and verify that cell EMF is strictly proportional to balancing length. Suggested independent settings: 0.4, 0.65, 0.9, 1.0186, 1.25, 1.5 V.
1Primary Working Driver Circuit Assembly and Continuity Verification
Connect the regulated 2.000 V driver accumulator in series with a master knife switch, an adjustable wirewound rheostat, and the 1-meter potentiometer slide wire AB. Ensure the positive terminal of the driver accumulator connects directly to binding post A (the zero of the metric scale). Close the switch and adjust the rheostat to set the potential drop across wire AB to slightly greater than the maximum cell EMF to be measured (setting the potential gradient to exactly k = 0.02000 V/cm).
Why this step matters
Establishing a uniform, unvarying potential drop across the slide wire is the foundational requirement for all subsequent potentiometric null measurements.
2Secondary Branch Connection with Opposing Polarities
Connect the positive terminal of the Weston cadmium standard cell (ℰ_s = 1.0186 V) to the common positive post A. Connect the negative terminal through the protective 10,000 Ω resistor and sensitive center-zero galvanometer to the movable knife-edge jockey slider F. Verify that the standard cell electromotive force directly opposes the potential drop along the slide wire from post A.
Why this step matters
Connecting identical polarities to common terminal A ensures that the potentiometer wire potential and the test cell EMF oppose each other at the jockey contact, making null balance possible.
3Two-End Polarity Reversal Diagnostic Test
Lightly touch the jockey contact to the extreme left of the wire near post A (ℓ ≈ 1 cm) and tap the galvanometer key, observing the direction of needle deflection. Next, touch the jockey to the extreme right near post B (ℓ ≈ 99 cm) and tap the key. Verify that the two deflections occur in opposite directions. If opposite deflections are not obtained, reverse the cell connections or reduce the driver rheostat resistance.
Why this step matters
Opposite galvanometer deflections at the wire extremes prove that the null balance point lies safely within the physical span of the slide wire and that polarities are correctly opposing.
4Standard Cell Calibration and Potential Gradient Determination
Use the method of successive approximations (bisection search) to locate the approximate null point with the 10,000 Ω protective resistor in series. Once the needle deflection is less than 1 scale division, depress the bypass key to short-circuit the protective resistor, and gently adjust the jockey position until the galvanometer rests at perfect zero. Record the standard cell balance length ℓ_s = 50.93 cm and compute the potentiometer potential gradient k = ℰ_s / ℓ_s = 1.0186 / 50.93 = 0.02000 V/cm (2.000 V/m).
Why this step matters
Calibrating against the certified Weston standard cell converts the linear geometric distance along the wire into an absolute thermodynamic potential scale.
5Sequential Unknown Cell EMF Null Balancing Runs
Switch the secondary branch to the unknown test cells using the selector switch, ensuring that the driver circuit rheostat remains completely untouched. For each of the six cell EMF levels (spanning 0.400 V to 1.500 V, including standard cell, Daniell cell, and dry cells), determine the precise balancing length ℓ_x at galvanometer null. Record the balancing length in centimeters and convert to meters (L_x = ℓ_x / 100.0).
Why this step matters
Keeping the primary driver current strictly constant throughout all runs preserves the calibrated potential gradient k across all cell comparisons.
6Linear Regression Analysis and Ratio Verification
Plot the balancing length L (in meters) on the horizontal axis and the cell electromotive force ℰ (in Volts) on the vertical axis. Compute ordinary least-squares linear regression to determine the potential gradient k (the slope m in V/m) and the vertical intercept b. Calculate the cell EMF ratios ℰ_x / ℰ_s and compare against the corresponding length ratios ℓ_x / ℓ_s to verify Poggendorff’s law of the potentiometer.
Why this step matters
Linear regression over multiple cell EMF stations confirms the spatial uniformity of the wire and filters out visual meniscus and contact resistance uncertainties.